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Lars: There is an error in the zip file above (version 2007-04-20). The directory pub/skins/exportdoc is labeled exportodoc in the Zip-File. Remove the o and it will work.
Be aware that this is a very simple export, it only passes the HTML on to MS Word.
You are right, I'll put togheter another zip file and upload it. ExportDOC a simple script and yes it passes HTML as a word document, I did the script because I saw the same functionality over confluence and I thought it was a Good Thing(tm) to have this for PmWiki as a recipe.